Asymmetric Total Synthesis of Stagonolide G

被引：11

作者：

Ramesh, Dasari ^{[1
]}

Rajaram, Singanaboina ^{[1
]}

Prabhakar, Peddikotla ^{[1
]}

Ramulu, Udugu ^{[1
]}

Reddy, Dorigondla Kumar ^{[1
]}

Venkateswarlu, Yenamandra ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Nat Prod Lab, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

HELVETICA CHIMICA ACTA | 2011年 / 94卷 / 07期

关键词：

STEREOSELECTIVE TOTAL-SYNTHESIS; STAGONOSPORA-CIRSII; POTENTIAL MYCOHERBICIDE; ARVENSE;

D O I：

10.1002/hlca.201000416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple asymmetric total synthesis of stagonolide G (1) is described. Asymmetric dihydroxylation, regioselective epoxide ring opening, and vinyl Grignard reactions are involved in generating the stereogenic centers C(4) and C(8), followed by Grubbs-II-catalyzed ring-closing metathesis (RCM).

引用

页码：1226 / 1233

页数：8

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