The use of divalent samarium iodide (SmI2) as a reducing agent has stimulated remarkable evolution in organic synthesis, which has been followed by the application of this chemistry to polymer science in the last ten pears. Here, we briefly summarize the exciting developments in which SmI2-induced electron transfer processes participate in key steps in polymerization reactions. We focus on the following systems: 1) transformation reaction from cationic to anionic growing centers by SmI2, 2) formation of bimetallic initiator through the reductive coupling of electrophilic monomers by SmI2, and 3) stepwise polymerization by the extension of carbon - carbon bond-forming reactions by SmI2.
机构:
Univ Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, FranceUniv Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, France
Sahloul, Kamar
Sun, Linhao
论文数: 0引用数: 0
h-index: 0
机构:
Univ Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, FranceUniv Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, France
Sun, Linhao
Requet, Alexandre
论文数: 0引用数: 0
h-index: 0
机构:
Univ Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, FranceUniv Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, France
Requet, Alexandre
Chahine, Youhana
论文数: 0引用数: 0
h-index: 0
机构:
Univ Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, FranceUniv Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, France
Chahine, Youhana
Mellah, Mohamed
论文数: 0引用数: 0
h-index: 0
机构:
Univ Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, FranceUniv Paris Sud, ICMMO, Equipe Catalyse Mol, UMR 8182, F-91405 Orsay, France
机构:
Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R ChinaZhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
Ye, Wei
Ding, Wenbo
论文数: 0引用数: 0
h-index: 0
机构:
Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R ChinaZhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
Ding, Wenbo
Hu, Zhang
论文数: 0引用数: 0
h-index: 0
机构:
Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R ChinaZhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
Hu, Zhang
Yu, Yongping
论文数: 0引用数: 0
h-index: 0
机构:
Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R ChinaZhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
Yu, Yongping
Zou, Hongbin
论文数: 0引用数: 0
h-index: 0
机构:
Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Beijing 100864, Peoples R ChinaZhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China