Synthesis, characterisation and catalytic activity of propionamide complexes of rare earth chlorides

被引：0
|
作者：
Qu, YH
Wang, XJ
Yu, W
Li, YL
Yu, GQ
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
[2] Changchun Normal Coll, Dept Chem, Changchun 130032, Peoples R China
来源：
JOURNAL OF RARE EARTHS | 1998年 / 16卷 / 04期
关键词：
rare earths; propionamide; butadiene polymerization; catalytic activity;
D O I：
暂无
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Propionamide complexes of rare earth chlorides were synthesized, Formula of the complexes is LnCl(3). 3BA. The ligand is shown to behave as a normal amide donor With the oxygen of the carbonyl group coordinated to the metal ions. Binary system composed Elf propionamide and aluminum alkyl shows higher activity and stereospecificity for butadiene polymerization. The cis-1,4 content of polybutadiene is more than 98%.
引用
收藏
页码：262 / 265
页数：4
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