Preparation and physical properties of N-defunctionalized derivatives of poly(aspartic acid)

被引：5
|
作者：
Katritzky, AR [1 ]
Yao, JC
Qi, M
Qiu, GF
Bao, WL
Yang, BZ
Denisko, O
Davis, S
Zhang, JG
机构：
[1] Univ Florida, Dept Chem, Ctr Heterocycl Cpds, Gainesville, FL 32611 USA
[2] Solutia Inc, St Louis, MO 63166 USA
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2001年 / 81卷 / 01期
关键词：
poly(aspartic acid); defunctionalization; silylation; absorbency;
D O I：
10.1002/app.1416
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A number of N-substituted poly(aspartic acid)s was prepared under mild conditions using the silylation-alkylation technique. Their physical properties were studied. Free swelling capacity (FSC) tests were performed for polymers obtained by crosslinking the parent poly(aspartic acid) as well as its defunctionalized derivatives. The hypothesis that H-bonding is critical in superabsorbency was demonstrated. (C) 2001 John Wiley & Sons, Inc.
引用
收藏
页码：85 / 90
页数：6
相关论文
共 50 条
  • [1] Properties and synthesis of poly(aspartic acid) and its derivatives
    Polaczek, J
    Dziki, E
    Pielichowski, J
    POLIMERY, 2003, 48 (01) : 61 - 65
  • [2] Preparation and properties of poly(aspartic acid)-based hydrogel
    Park, HD
    Kim, JH
    Kim, SH
    Kim, YH
    POLYMER-KOREA, 1999, 23 (02) : 247 - 254
  • [3] Preparation and Characterization of Poly(aspartic Acid) Derivatives as Biodegradable Water Treatment Agents
    Huang, Kai
    Kong, Li
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (18) : 10233 - 10237
  • [4] Poly(aspartic acid) - properties and applications
    Dziki, E
    Pielichowski, J
    Polaczek, J
    PRZEMYSL CHEMICZNY, 2005, 84 (01): : 18 - 21
  • [5] Preparation and physical properties of thermoresponsive biodegradable poly(asparagine) derivatives
    Watanabe, E
    Tomoshige, N
    CHEMISTRY LETTERS, 2005, 34 (06) : 876 - 877
  • [6] Methods of analysis of poly(aspartic acid) and its derivatives
    Tylek, E
    Polaczek, J
    Pielichowski, J
    POLIMERY, 2005, 50 (05) : 341 - 345
  • [7] Possibilities for poly(aspartic acid) preparation as biodegradable compound
    Nita, LE
    Chiriac, AP
    Popescu, CM
    Neamtu, I
    Alecu, L
    JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 2006, 8 (02): : 663 - 666
  • [8] Efficient preparation of β-hydroxy aspartic acid and its derivatives
    Liu, Long
    Wang, Bo
    Bi, Cheng
    He, Gang
    Chen, Gong
    CHINESE CHEMICAL LETTERS, 2018, 29 (07) : 1113 - 1115
  • [9] Preparation of interpenetrating polymer networks of poly(aspartic acid) and poly(acrylic acid) salts with hydrogel-like properties
    Grzesik, Ryszard
    Lukosek, Marek
    Torchala, Kamila
    Kotyrba, Lukasz
    Wojcik, Jan
    PRZEMYSL CHEMICZNY, 2020, 99 (12): : 1712 - 1716
  • [10] Efficient preparation of β-hydroxy aspartic acid and its derivatives
    Long Liu
    Bo Wang
    Cheng Bi
    Gang He
    Gong Chen
    Chinese Chemical Letters, 2018, 29 (07) : 1113 - 1115
12345