Morphology, Thermal and Mechanical Properties of Biodegradable Poly(butylene succinate)/Poly(butylene adipate-co-terephthalate)/Clay Nanocomposites

被引:27
|
作者
Ibrahim, N. A. [1 ]
Chieng, B. W. [1 ]
Yunus, W. M. Z. Wan [1 ]
机构
[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, Malaysia
关键词
Biodegradable; Nanocomposite; Organoclay; MODIFIED LAYERED SILICATE; POLYMER BLENDS; POLYPROPYLENE; MONTMORILLONITE; RUBBER; EPOXY;
D O I
10.1080/03602559.2010.512337
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sodium montmorillonite (Na-MMT) was successfully modified by octadecylamine (ODA) through a cation exchange technique that showed by the increased of basal spacing of clay by XRD. The addition of the organoclay into the PBS/PBAT blends produced intercalated-type nanocomposites with improvements in tensile modulus and strength. The highest tensile strength of nanocomposite was observed at 1wt% of organoclay incorporated. A TGA study showed that the thermal stability of the blend increased after the addition of the organoclay by 1wt%. SEM micrographs of the fracture surfaces show that the morphology of the blend becomes smoother with presence of organoclay.
引用
收藏
页码:1571 / 1580
页数:10
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