Local trapping of energetic holes at gold nanoparticles on TiO2

被引:28
|
作者
Nishi, Hiroyasu [1 ]
Sakamoto, Masumi [1 ]
Tatsuma, Tetsu [1 ]
机构
[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan
基金
日本学术振兴会;
关键词
INDUCED CHARGE SEPARATION; HOT-ELECTRON; PHOTOCHEMICAL OXIDATION; REDUCTION REACTIONS; SILVER NANOCUBES; PLASMON; SURFACE; POLYMERIZATION; GENERATION; EVOLUTION;
D O I
10.1039/c8cc06413j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Oxidation sites for plasmon-induced charge separation at gold nanocubes and nanorods on TiO2 were visualized by PbO2 deposition, and the sites were localized at plasmonic resonance sites. This indicates that energetic holes generated at those sites dominate the reactions, which can be applied to photo-nanofabrication beyond the diffraction limit.
引用
收藏
页码:11741 / 11744
页数:4
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