Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2-carboxylate)-bridged manganese polymer

被引：37
|
作者：
Chen, LF [1 ]
Zhang, J [1 ]
Song, LJ [1 ]
Ju, ZF [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 06期
基金：
中国国家自然科学基金;
关键词：
manganese(II) complex; 1,4,5,8-naphthalenetetracarboxylate; magnetic; crystal structure; coordination polymer;
D O I：
10.1016/j.inoche.2005.03.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A manganese coordination polymer [Mn-2(NTC)(H2O)(2)](n), where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：555 / 558
页数：4
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