Pentagonal-dodecahedral La2 charge density in [80-Ih]fullerene:: La2@C80

被引：0
|
作者：
Nishibori, E
Takata, M [1 ]
Sakata, M
Taninaka, A
Shinohara, H
机构：
[1] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
[2] Nagoya Univ, Dept Chem, Nagoya, Aichi 4648602, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 16期
关键词：
fullerenes; lanthanum; structure elucidation; synchrotron radiation; X-ray diffraction;
D O I：
10.1002/1521-3773(20010817)40:16<2998::AID-ANIE2998>3.0.CO;2-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A double shell of Platonic solids: A trajectory that connects the six-numbered rings of Ih-C80 is followed by the two La atoms of La2@C80 according to maximum entropy/Rietveld analysis of the synchtron powder-diffraction data. The result is a pentagonal-dodecahedral charge-density distribution for La2 (brown in the picture) inside the icodsahedral C80 cage (green).
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收藏
页码：2998 / 2999
页数：2
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