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Synthesis and Self-Assembly of Oligo(p-phenylenevinylene) Peptide Conjugates in Water
被引:38
|作者:
Mba, Miriam
Moretto, Alessandro
Armelao, Lidia
[1
]
Crisma, Marco
[2
]
Toniolo, Claudio
Maggini, Michele
[1
]
机构:
[1] Univ Padua, Dept Chem Sci, ISTM CNR, INSTM, I-35131 Padua, Italy
[2] Univ Padua, Dept Chem Sci, CNR, Padova Unit,ICB, I-35131 Padua, Italy
关键词:
aggregation;
gels;
oligo(p-phenylenevinylene)s;
peptides;
self-assembly;
ENERGY-TRANSFER;
NANOSTRUCTURES;
ORGANOGELS;
SPECTRA;
D O I:
10.1002/chem.201002495
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Fluorescent hydrogels: Peptide hybrids composed of an oligo(p- phenylenevinylene)-based τ-amino acid and a β-sheet-forming sequence reversibly self-assemble into fluorescent hydrogels upon a change in pH (see graphic). This study highlights how the combination of peptides and π-conjugated oligomers could be a fruitful approach towards the control of self-assembled structures. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:2044 / 2047
页数:4
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