N-Heterocyclic carbene catalysed aerobic oxidation of aromatic aldehydes to aryl esters using boronic acids

被引：41
|
作者：
Arde, Panjab [1 ]
Ramanjaneyulu, B. T. [1 ]
Reddy, Virsinha [1 ]
Saxena, Apurv [1 ]
Anand, R. Vijaya [1 ]
机构：
[1] Indian Inst Sci Educ & Res IISER Mohali, Sect 81, Manuali 140306, Punjab, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 04期
关键词：
CARBOXYLIC-ACIDS; ALPHA; BETA-UNSATURATED ALDEHYDES; ESTERIFICATION; ALCOHOLS; CARBONYLATION; CO2;
D O I：
10.1039/c1ob06566a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.
引用
收藏
页码：848 / 851
页数：4
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