Synthesis and characterizations of new cationic Fe(III), Co(II) and Ni(II) complexes containing isatin/triphenylphosphine mixed ligands

被引：2
|
作者：
Al-Resayes, SI [1 ]
机构：
[1] King Saud Univ, Dept Chem, Riyadh 11451, Saudi Arabia
来源：
SPECTROSCOPY LETTERS | 1999年 / 32卷 / 02期
关键词：
Chelation - Cobalt compounds - Complexation - Iron compounds - Nickel compounds - Synthesis (chemical);
D O I：
10.1080/00387019909349986
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
New cationic Fe(III),Co(II) and Ni(II) mixed ligand complexes containing both triphenylphosphine and isatin ligands were prepared and characterized using conventional physical and chemical methods of analysis, (I.R., UV-Vis., and H-1 NMR). Microanalytical data of the investigated complexes are consistent with the formulations. [Fe(Isa)(2) {P(Ph)(3)}(2)](3+), [Co(lsa)(2) {P(Ph)(3)}(2)](2+) and [Ni(Isa)(2) {P(Ph)(3)}(2)](2+), (Where Isa = Isatin and P(Ph)(3) = Triphenylphosphine). The prepared complexes are soluble in polar solvents and could be of potential use in bio-inorganic applications.
引用
收藏
页码：315 / 319
页数：5
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