Polyaniline assisted by TiO2:SnO2 nanoparticles as a hydrogen gas sensor at environmental conditions

被引:46
|
作者
Nasirian, Shahruz [1 ]
Moghaddam, Hossain Milani [1 ]
机构
[1] Univ Mazandaran, Dept Solid State Phys, Babol Sar, Iran
关键词
Polyaniline/TiO2:SnO2 nanocomposite; Emeraldine; Metal oxide nanoparticles; Hydrogen gas sensor; Environmental conditions; NANOCOMPOSITE; SURFACE; HYBRID; POLYMERIZATION; SCIENCE;
D O I
10.1016/j.apsusc.2014.12.051
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present research, polyaniline assisted by TiO2:SnO2 nanoparticles was synthesized and deposited onto an epoxy glass substrate with Cu-interdigited electrodes for gas sensing application. To examine the efficiency of the polyaniline/TiO2:SnO(2)nanocomposite (PTS) as a hydrogen (H-2) gas sensor, its nature, stability, response, recovery/response time have been studied with a special focus on its ability to work at environmental conditions. H-2 gas sensing results demonstrated that a PTS sensor with 20 and 10 wt% of anatase-TiO2 and SnO2 nanoparticles, respectively, has the best response time (75 s) with a recovery time of 117s at environmental conditions. The highest (lowest) response (recovery time) was 6.18 (46s) in PTS sensor with 30 and 15 wt% of anatase- (rutile-)TiO2 and SnO(2)nanoparticles, respectively, at 0.8 vol.% H2 gas. Further, the H2 gas sensing mechanism of PTS sensor has also been studied. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:395 / 404
页数:10
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