(1,4,7,10-Tetraazacyclododecane-κ4 N 1,N 4,N 7,N 10)(tetraoxidomolybdato-κO)copper(II) monohydrate

被引：2

作者：

Rohde, Dorothea ^{[1
]}

Merzweiler, Kurt ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Chem, Nat Wisssench Fak 2, D-06120 Halle, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

COMPLEXES; LIGANDS;

D O I：

10.1107/S1600536810026000

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [CuMoO4(C8H20N4)]center dot H2O, the CuII atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form centrosymmetric dimers [R (4) 4(12) and R (4) 4(16)] and discrete D (3) 2(9), D (3) 3(11) and D (3) 3(13) chains by O-H...O and N-H...O interactions. Additionally, the complex molecules are linked into C (4) 4(18) chain motifs by N-H...O interactions. As a result [(cyclen)CuMoO4] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C-H...O hydrogen bridges.

引用

页码：M894 / U351

页数：13

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