One-pot synthesis of donor-acceptor [2]rotaxanes based on cryptand-paraquat recognition motif

被引：16

作者：

Xu, Zhikai ^{[1
]}

Jiang, Lasheng ^{[1
]}

Feng, Yahui ^{[1
]}

Zhang, Suhui ^{[1
]}

Liang, Jidong ^{[1
]}

Pan, Shaowu ^{[1
]}

Yang, Yu ^{[1
]}

Yang, Dengke ^{[1
]}

Cai, Yuepeng ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510631, Guangdong, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 04期

基金：

中国国家自然科学基金;

关键词：

BIS(CROWN ETHER) HOST; BETA-CYCLODEXTRIN; SUPRAMOLECULAR CHEMISTRY; POLYMERIC ROTAXANE; OLEFIN METATHESIS; ASSEMBLY BEHAVIOR; BORROMEAN RINGS; TACO COMPLEX; DERIVATIVES; GUEST;

D O I：

10.1039/c0ob00629g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two novel cryptand-based [2]rotaxanes were synthesized by a facile one-pot reaction from three neutral precursors: easily accessible cryptand host 1 and commercially available 4,4'-bipyridine and 3,5-di-tert-butylbenzyl bromide. Their structures were confirmed by H-1 NMR, 2D NMR, HRMS and X-ray analysis. Moreover, two [2]pseudorotaxanes based on the same cryptand hosts and dibenzyl viologen guest 3 were also demonstrated both in solution and in the solid state, which are different from previously reported [3]pseudorotaxane-like complexes formed by dimethyl viologen guest 2 and the cryptands.

引用

页码：1237 / 1243

页数：7

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