Reactions of (η5-indenyl)Ru(PPh3)2Cl with CH2Cl2 and CHCl3:: Formation of (η5-indenyl)Ru{CH2PPh2(C6H4)}(PBh3) and (η5-indenyl) Ru(PPh3)(CO)Cl

被引:16
|
作者
Park, JH [1 ]
Koh, JH [1 ]
Park, J [1 ]
机构
[1] Pohang Univ Sci & Technol, POSTECH, Ctr Integrated Mol Syst, Dept Chem, Pohang 790784, South Korea
关键词
D O I
10.1021/om001003n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A cyclic phoshorus ylide complex, (eta (5)-indenyl)Ru{CH2PPh2(C6H4)}(PPh3) (2), and (eta (5)-indenyl)Ru(PPh3)(CO)Cl (3) were formed in the reactions of (eta (5)-indenyl)Ru(PPh3)(2)Cl (1) with CH2Cl2 and CHCl3 in the presence of KOH and 2-propanol, respectively.
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页码:1892 / 1894
页数:3
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