Transition metal-catalyzed [2,3]-sigmatropic rearrangements of ylides: An update of the most recent advances

被引:115
|
作者
Sheng, Zhe [1 ,2 ]
Zhang, Zhikun [1 ]
Chu, Changhu [2 ]
Zhang, Yan [1 ]
Wang, Jianbo [1 ]
机构
[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
[2] East China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab New Drug Design, 130 Meilong Rd, Shanghai 200237, Peoples R China
关键词
Transition-metal-catalysis; Metal carbene; Ylide; Diazo compounds; 2,3]-sigmatropic rearrangement; OXO GOLD CARBENES; C BOND FORMATION; RHODIUM(II)-CATALYZED STEREOCONTROLLED SYNTHESIS; 2,3 SIGMATROPIC REARRANGEMENT; OXONIUM YLIDE; STEREOSELECTIVE-SYNTHESIS; DONOR/ACCEPTOR CARBENOIDS; TANDEM YLIDE; N-TOSYLHYDRAZONES; DIAZO-COMPOUNDS;
D O I
10.1016/j.tet.2016.11.045
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[2,3]-sigmatropic rearrangements of ylides are useful methods for synthesizing functional molecules, especially for these containing heteroatoms. This short report focuses on the most recent advances in transition-metal-catalyzed [2,3]-sigmatropic rearrangements of sulfonium, oxonium, and ammonium ylides. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4011 / 4022
页数:12
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