Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

被引：12

作者：

Kotha, Sambasivarao ^{[1
]}

Gunta, Rama ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay, Maharashtra, India

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 12卷

关键词：

norbornene; propellane derivatives; ring-closing metathesis; single-crystal X-ray diffraction; vicinal diallylation; DIELS-ALDER REACTION; REARRANGEMENT METATHESIS; CLAISEN REARRANGEMENT; KEY STEPS; OLEFIN METATHESIS; MOLECULAR FRAMEWORKS; OPENING METATHESIS; CAGE COMPOUNDS; DESIGN; QUINONES;

D O I：

10.3762/bjoc.12.177

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.

引用

页码：1877 / 1883

页数：7

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