Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

被引：23
|
作者：
Nunokawa, K
Onaka, S
Yamaguchi, T
Ito, T
Watase, S
Nakamoto, M
机构：
[1] Nagoya Inst Technol, Grad Sch Engn, Dept Environm Technol, Showa Ku, Nagoya, Aichi 4668555, Japan
[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
[3] Osaka Municipal Tech Res Inst, Joto Ku, Osaka 5368553, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 08期
关键词：
D O I：
10.1246/bcsj.76.1601
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new An, I cluster with (m-CF3C6H4)(3)P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR3)(7) clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
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收藏
页码：1601 / 1602
页数：2
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