{Tc(NO)(Cp)(PPh3)}+ - a novel technetium(I) core

被引：14
|
作者：
Ackermann, J. [1 ]
Hagenbach, A. [1 ]
Abram, U. [1 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 67期
关键词：
RAY STRUCTURAL-ANALYSIS; ORGANOMETALLIC COMPOUNDS; CRYSTAL-STRUCTURE; RHENIUM; COMPLEXES; CHEMISTRY; METAL; RE; TRIS(CYCLOPENTADIENYL)TECHNETIUM(III); RADIOMETALS;
D O I：
10.1039/c6cc05811f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions between [TcI(NO)X-2(PPh3)(2)(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(I) compounds with the robust {Tc(NO)(Cp)(PPh3)}(+) core.
引用
收藏
页码：10285 / 10288
页数：4
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