High-Temperature Passivation of the Surface of Candidate Materials for MSR by Adding Oxygen Ions to FLiNaK Salt

被引:6
|
作者
Karfidov, Eduard A. [1 ]
Zaikov, Yuri P. [1 ]
Nikitina, Evgenia, V [1 ]
Seliverstov, Konstantin E. [1 ]
Dub, Alexey, V [2 ]
机构
[1] Russian Acad Sci, Inst High Temp Electrochem, Ural Branch, Ekaterinburg 620066, Russia
[2] Natl Univ Sci & Technol MISIS, Moscow 119049, Russia
关键词
corrosion; candidate materials for MSR; FLiNaK melt; high-temperature passivation; protective oxide layers; LIF-NAF-KF; MOLTEN FLUORIDES; CORROSION; CHLORIDE;
D O I
10.3390/ma15155174
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The problem of tailoring the structural materials for MSR is solved by continuously overcoming the shortcomings of widely used materials and finding new ones. The materials commonly used in engineering may not be applicable for MSR due to their high corrosivity. Experiments were carried out to determine the corrosion rate of stainless steel 12Cr18Ni10Ti with different concentrations of oxide ions (by adding lithium oxide to the melt in the concentration range from 0 to 0.8 wt.%) in a FLiNaK melt. The formation of a protective oxygen-containing layer with a thickness of 1 micron has been realized. The corrosion rate decreases by an order of magnitude at the concentration of oxygen anions in the melt, in the range from 0.2 to 0.4% by weight, which may indicate high-temperature passivation of the material due to modification of the composition of the fluoride melt and reduction in its corrosion activity. In addition, the corrosion type of stainless steel in fluoride melts changes from the intercrystalline and pitting that is usually harmful to reactor material structure to total corrosion when lithium oxide is added. This is due to the "healing" of individual corrosion defects formed on the surface of the studied material by oxygen-containing compounds.
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页数:8
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