A convenient synthesis of the side-chain of sterols

被引：11
|
作者：
Schmittberger, T [1 ]
Uguen, D [1 ]
机构：
[1] ECOLE EUROPEENNE HAUTES ETUD IND CHIM,CNRS,ORGAN SYNTH LAB,F-67008 STRASBOURG,FRANCE
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 01期
关键词：
D O I：
10.1016/0040-4039(95)02075-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Potassium t-butoxide-induced Ramberg-Backlund rearrangement of chlorosulfones formed from a cyclopregnane-20-thiomethanol derivative has been shown to give Delta(22)-unsaturated steroids with high trans stereoselectivity.
引用
收藏
页码：29 / 32
页数：4
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