Some properties of microcanonical rate constants

被引:11
|
作者
Klots, CE
机构
[1] Chemical and Biological Physics Section, Oak Ridge National Laboratory, Oak Ridge, TN, 37831-6125
关键词
D O I
10.1080/01442359609353181
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An isolated body is characterized by conserved properties such as its energy and angular momentum. The rates of processes occurring in that body can thus be investigated as a function of these properties. On the other hand the rates may be better known, both conceptually and experimentally, as a function of temperature. This paper surveys relations between rate descriptions in the two domains, as deduced using steepest descent techniques. The rudiments of these techniques are given in an appendix.
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页码:205 / 217
页数:13
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