Bis(2-aminopyridine)(2,2′-bipyridine)platinum(II) tetracyanoplatinate(II) dlhydrate

被引：7
|
作者：
Sakai, K [1 ]
Mizota, M [1 ]
Akiyama, N [1 ]
机构：
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536803028332
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Pt(C10H8N2)(C5H6N2)(2)][Pt(CN)(4)].2H(2)O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the pi-pi stacking associations between the 2,2'-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt...Pt distances [5.2034 (6) and 4.5599 (6) Angstrom] alternate along the one-dimensional stack.
引用
收藏
页码：M88 / M90
页数：3
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