Synthesis, characterization, and catalytic activity of a water soluble copper(II) and nickel(II) heterobimetallic complex [CuNi(-OH)(-OH2)(-OAc)(bpy)2](ClO4)2 in aqueous medium in the absence of a base and co-catalyst

被引：3
|
作者：
Lal, Ram A. [1 ]
Kumar, Arvind [2 ]
Syiemlieh, Ibanphylla [1 ]
Kurbah, Sunshine D. [1 ]
机构：
[1] North Eastern Hill Univ, Dept Chem, Ctr Adv Studies, Shillong, India
[2] Univ West Indies, Fac Sci & Technol, Dept Chem, St Augustine, Trinidad Tobago
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 70卷 / 15期
关键词：
Heterobimetallic; CuNi(-OH)(-OH2)(-OAc)(bpy)(2)](ClO4)(2); selective oxidation; AEROBIC ALCOHOL OXIDATION; AMPHIPHILIC RESIN-DISPERSION; METAL-ORGANIC FRAMEWORKS; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; BENZYLIC ALCOHOLS; HIGHLY EFFICIENT; SECONDARY ALCOHOLS; MECHANISTIC INVESTIGATIONS; MANGANESE(III) COMPLEXES;
D O I：
10.1080/00958972.2017.1358812
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A copper(II)-nickel(II)-based catalyst system has been synthesized and characterized by elemental analysis, molar conductance, mass spectra, magnetic moment, EPR, UV-Vis, IR spectroscopy, and cyclic voltammetry. The structure of the complex was established by X-ray crystallography. The complex is an efficient catalyst, which oxidizes primary and secondary alcohols to the corresponding aldehydes and ketones at 70 degrees C employing 15% H2O2 as the oxidant in the absence of a base and co-catalyst. [GRAPHICS] .
引用
收藏
页码：2722 / 2735
页数：14
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