Synthesis of Zinc Isonicotinates by Solid-state Reactions: A Green Route to Coordination Polymers

被引：2

作者：

Chen, Jinxi ^{[1
]}

Zhang, Ruobing ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 01期

关键词：

METAL-ORGANIC FRAMEWORKS; SOLVENT-FREE SYNTHESIS; REACTIVITY; COMPLEXES; MECHANISM; DESIGN; 1D;

D O I：

10.1246/cl.2011.56

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two known coordination polymers, Zn(INA)(2) and Zn(INA)(2)center dot 2H(2)O (INA: isonicotinate), have been synthesized through solid-state reactions that are more efficient and environmentally friendly than conventional methods. By varying the reaction conditions, the solid-state reactions between the metal salt and bridging ligand could be rationally controlled to give different polymeric three-dimensional structures or a mononuclear coordination compound.

引用

页码：56 / 57

页数：2

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