High temperature oxidation behaviors of SiON coated AISI 441 in Ar + O2, Ar + H2O, and Ar + CO2 atmospheres

被引：14

作者：

Bawane, Kaustubh ^{[1
]}

Lu, Kathy ^{[1
]}

Li, Quan ^{[2
]}

Bordia, Rajendra ^{[2
]}

机构：

[1] Virginia Polytech Inst & State Univ, Dept Mat Sci & Engn, Blacksburg, VA 24061 USA

[2] Clemson Univ, Dept Mat Sci & Engn, Clemson, SC 29634 USA

来源：

CORROSION SCIENCE | 2020年 / 166卷

基金：

美国国家科学基金会;

关键词：

Oxidation resistant coating; SiON; Ferritic stainless steel; Diffusion; Atmosphere; ENVIRONMENTAL BARRIER COATINGS; STAINLESS-STEEL; PART I; POLYMER; PERFORMANCE; PRECURSORS; PROTECTION; CORROSION; SYSTEM; CARBONITRIDE;

D O I：

10.1016/j.corsci.2020.108429

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Silicon oxynitride (SiON) coated AISI 441 was prepared by pyrolysis of a dip-coated perhydropolysilazane (PHPS) precursor polymer. The high temperature oxidation behaviors of SiON coated AISI 441 substrates were studied in Ar + O-2, Ar + H2O, and Ar + CO2 atmospheres at 800 degrees C for 100 h. The SiON coated AISI substrates showed better performance in all three atmospheres compared to the uncoated AISI 441 substrate. This improvement was attributed to the dense, crack-free SiON coatings, which provided complete separation between oxidizing species and the steel substrate. A thin oxide scale was observed on top of the SiON coating for all the atmospheres, which was attributed to the reactions between the oxidizing species in the atmosphere and the metallic species (Cr, Mn, and Fe) diffused through the SiON coating from the AISI 441 substrate.

引用

页数：7

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