Amines free environmentally friendly rapid synthesis of Cu2SnS3 nanoparticles

被引：32
|
作者：
Lokhande, A. C. [1 ]
Pawar, S. A. [1 ]
Jo, Eunjin [1 ]
He, Mingrui [1 ]
Shelke, A. [2 ]
Lokhande, C. D. [2 ]
Kim, Jin Hyeok [1 ]
机构：
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Optoelect Convergence Res Ctr, Gwangju 500757, South Korea
[2] Shivaji Univ, Dept Phys, Thin Film Phys Lab, Kolhapur 416004, MS, India
来源：
OPTICAL MATERIALS | 2016年 / 58卷
基金：
新加坡国家研究基金会;
关键词：
Cu2SnS3; Nanoparticles; Band gap; Hot injection; Sulfur source; IONIC LAYER ADSORPTION; SOLAR-CELL; THIN-FILMS; OPTICAL-PROPERTIES; CTS NANOPARTICLES; NANOCRYSTALS;
D O I：
10.1016/j.optmat.2016.03.032
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Cubic and tetragonal structured Cu2SnS3 (CTS) nanoparticles are rapidly synthesized within a short reaction time of 5 min using low cost amine free octadecene (ODE) solvent by hot injection technique. The effects of precursor concentration, sulfur source and reaction time on the CTS nanoparticle synthesis are studied. The crystal structure, size, phase purity, atomic composition, oxidation state and optical properties of these nanoparticles are studied in detail by X-ray diffraction (XRD), transmission electron microscopy (TEM), Raman, energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS) and UV-visible spectroscopy techniques. Spherical shaped particles in the size range of 25-30 nm are obtained with atomic composition in close agreement with the stoichiometry of Cu2SnS3. The reaction mechanism of CTS nanoparticle formation is proposed. The synthesized cubic and tetragonal structured CTS nanoparticles exhibit optimal band gaps of 1.23 eV and 1.45 eV, respectively, suitable for use in photovoltaic applications. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：268 / 278
页数：11
相关论文
共 50 条
  • [1] Controlled solvothermal synthesis and properties of Cu2SnS3 nanoparticles
    Rabaoui, S.
    Dahman, H.
    Omri, K.
    Dekhil, S.
    El Mir, L.
    Vazquez-Vazquez, C.
    Lopez-Quintela, M. A.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (03) : 3090 - 3097
  • [2] Controlled solvothermal synthesis and properties of Cu2SnS3 nanoparticles
    S. Rabaoui
    H. Dahman
    K. Omri
    S. Dekhil
    L. El Mir
    C. Vázquez-Vázquez
    M. A. López-Quintela
    Journal of Materials Science: Materials in Electronics, 2017, 28 : 3090 - 3097
  • [3] Microwave-assisted rapid synthesis of tetragonal Cu2SnS3 nanoparticles for solar photovoltaics
    Tiwari, Devendra
    Chaudhuri, Tapas K.
    Shripathi, T.
    Deshpande, U.
    Sathe, V. G.
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 117 (03): : 1139 - 1146
  • [4] Microwave-assisted rapid synthesis of tetragonal Cu2SnS3 nanoparticles for solar photovoltaics
    Devendra Tiwari
    Tapas K. Chaudhuri
    T. Shripathi
    U. Deshpande
    V. G. Sathe
    Applied Physics A, 2014, 117 : 1139 - 1146
  • [5] Rapid mechanochemical synthesis of nanostructured mohite Cu2SnS3 (CTS)
    Matej Baláž
    Nina Daneu
    Michal Rajňák
    Juraj Kurimský
    Michal Hegedüs
    Erika Dutková
    Martin Fabián
    Mária Kaňuchová
    Peter Baláž
    Journal of Materials Science, 2018, 53 : 13631 - 13642
  • [6] Rapid mechanochemical synthesis of nanostructured mohite Cu2SnS3 (CTS)
    Balaz, Matej
    Daneu, Nina
    Rajnak, Michal
    Kurimsky, Juraj
    Hegedus, Michal
    Dutkova, Erika
    Fabian, Martin
    Kanuchova, Maria
    Balaz, Peter
    JOURNAL OF MATERIALS SCIENCE, 2018, 53 (19) : 13631 - 13642
  • [7] Chemical synthesis of Cu2SnS3 (CTS) nanoparticles: A status review
    Lokhande, A. C.
    Gurav, K. V.
    Jo, Eunjin
    Lokhande, C. D.
    Kim, Jin Hyeok
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 656 : 295 - 310
  • [8] Synthesis, characterization, and properties of nanocrystalline Cu2SnS3
    Li, B
    Xie, Y
    Huang, JX
    Qian, YT
    JOURNAL OF SOLID STATE CHEMISTRY, 2000, 153 (01) : 170 - 173
  • [9] Facile hydrothermal synthesis of Cu2SnS3 nanoparticles for photocatalytic dye degredation of mythelene blue
    Machale, Archana R.
    Phaltane, Shilpa A.
    Shelke, Harshad D.
    Kadam, Laxman D.
    MATERIALS TODAY-PROCEEDINGS, 2021, 43 : 2768 - 2773
  • [10] Novel antibacterial application of photovoltaic Cu2SnS3 (CTS) nanoparticles
    Lokhande, A. C.
    Shelke, A.
    Babar, P. T.
    Kim, Jihun
    Lee, Dong Ju
    Kim, Il-Chul
    Lokhandee, C. D.
    Kim, Jin Hyeok
    RSC ADVANCES, 2017, 7 (54): : 33737 - 33744
12345