A solid-state supramolecular rotator assembled front a Cs-crown ether polyoxometalate hybrid:: (Cs+)3([18]crown-6)3(H+)2[PMo12O40]

被引：43

作者：

Akutagawa, Tomoyuki ^{[1
,2
,3
]}

Endo, Daigoro ^{[2
]}

Kudo, Fumito ^{[2
]}

Noro, Shin-ichiro ^{[1
,2
]}

Takeda, Sadamu ^{[4
]}

Cronin, Leroy ^{[5
]}

Nakamura, Takayoshi ^{[1
,2
,3
]}

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[2] Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido, Japan

[3] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan

[4] Hokkaido Univ, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

[5] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 03期

关键词：

D O I：

10.1021/cg060951+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solid-state molecular rotator comprising [18]crown-6 was assembled into a crystalline array of (Cs+)(3)([18]crown-6)(3)(H+)(2) [PMo12O40](5-) whereby two Cs+([18]crown-6) supramolecular rotators were complexed with a two-electron-reduced alpha-[PMo12O40](5-) Keggin cluster. The size-compatible rotators of [18]crown-6 were directly complexed to an alpha-[PMo12O40](5-) axle through Cs+-O interactions. The investigation of the dynamics of the system revealed that two rotation frequencies for [18]crown-6 were observed by using temperature-dependent H-1 NMR studies, and these were dominated by intermolecular interactions in the solid state.

引用

页码：812 / 816

页数：5

共 35 条

[1] Supramolecular Structural Inorganic-organic Hybrid [(4-Bromoanilimiun)([18]crown-6)]3[PMo12O40]•CH3CN
Zhang Yu-Heng
Cao Sheng
Lu Shao-Fang
Xiong Jun
[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (08) : 1272 - 1278
[2] Supramolecular Structural Inorganic-organic Hybrid[(4-Bromoanilimiun)([18]crown-6)]3[PMo12O40]·CH3CN
张裕恒
曹晟
吕少仿
熊俊
[J]. Chinese Journal of Structural Chemistry, 2018, 37 (08) : 1272 - 1278
[3] Molecular rotor of Cs2([18]crown-6)3 in the solid state coupled with the magnetism of [Ni(dmit)2]
Akutagawa, T
Shitagami, K
Nishihara, S
Takeda, S
Hasegawa, T
Nakamura, T
Hosokoshi, Y
Inoue, K
Ikeuchi, S
Miyazaki, Y
Saito, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (12) : 4397 - 4402
[4] An alkali metal-crown ether complex supported by a Keggin anion through the three terminal oxygen atoms in a single M3O13 triplet:: Synthesis and characterization of [{Na(dibenzo-18-crown-6)(MeCN)}3{PMo12O40}]
You, WS
Wang, EB
Xu, Y
Li, YG
Xu, L
Hu, CW
[J]. INORGANIC CHEMISTRY, 2001, 40 (21) : 5468 - 5471
[5] Crystal Structure and Blue Fluorescence of a New Inorganic-Organic Hybrid Polyoxometalate (3-C6H8N)4(PMo12O40)•H2O
Peng, Zhen-Shan
Huang, Yi-Lan
Lu, Shu-zi
Tang, Jian-Ting
Cai, Tie-Jun
Deng, Qian
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (03) : 376 - 382
[6] Reactions of Polyarsenides with Acetylene: Synthesis and Characterization of [Cs([18]crown-6)]2As7C14H11•6NH3 and As2C6H6
Grassl, Tobias
Friedrich, Ute
Kaas, Marina
Korber, Nikolaus
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (07): : 1203 - 1206
[7] A molecule based on polyoxometalate acid and crown ether:: synthesis and characterization of [(H3O)(C20H24O6)]2[HPMO12O40]•C20H24O6•3MeCN•H2O (C20H24O6 = dibenzo-18-crown-6)
You, WS
Wang, EB
Xu, L
Zhu, ZM
Gu, YP
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2002, 605 (01) : 41 - 49
[8] Carbonylation of dimethyl ether on solid Rh-promoted Cs-salt of Keggin 12-H3PW12O40: A solid-state NMR study of the reaction mechanism
Luzgin, Mikhail V.
Kazantsev, Maxim S.
Volkova, Galina G.
Wang, Wei
Stepanov, Alexander G.
[J]. JOURNAL OF CATALYSIS, 2011, 277 (01) : 72 - 79
[9] Synthesis and crystal structure of a new supermolecular compound:: [C12H24O6][H3PMo12O40]•22H2O (C12H24O6=18-crown-6)
You, WS
Wang, EB
He, QL
Xu, L
Xing, Y
Jia, HQ
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2000, 524 : 133 - 139
[10] Dimensions of the ozonide anion in M([18]crown-6)O3 • x NH3 with M = K (x=2), Rb (x=1) and Cs (x=8)
Nuss, Hanne
Nuss, Juergen
Jansen, Martin
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (08): : 1291 - 1295

← 1 2 3 4 →