Europium(II) and ytterbium(II) aryloxide chemistry:: synthesis and crystal structure of [Eu(OC6H3Bu2t-2,6)2(THF)3]•0.75C7H8 and [Yb(OC6H3Bu2t-2,6)2(NCMe)4]

被引：12
|
作者：
Carretas, J [1 ]
Branco, J [1 ]
Marçalo, J [1 ]
Domingos, K [1 ]
de Matos, AP [1 ]
机构：
[1] Inst Tecnol & Nucl, Dept Quim, P-2686953 Sacavem, Portugal
来源：
POLYHEDRON | 2003年 / 22卷 / 11期
关键词：
europium; ytterbium; MVS; dissolution in ammonia; aryloxides;
D O I：
10.1016/S0277-5387(03)00193-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of europium and ytterbium with 2,6-di-tert-butylphenol were studied by the metal vapour synthesis technique and by dissolution in liquid ammonia. The lanthanide complexes [Eu(OC6H3Bu2'-2,6)(2)(THF)(3)].0.75C(7)H(8) I and [Yb(OC6H3Bu2'-2,6)(2)(NCMe)(4)] 2 were synthesized and characterized by X-ray diffraction studies. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码：1425 / 1429
页数：5
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