Suzuki-Miyaura cross-coupling of potassium trifluoroboratohomoenolates

被引：63

作者：

Molander, Gary A. ^{[1
]}

Petrillo, Daniel E. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana A Vagelos Labs, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 09期

关键词：

D O I：

10.1021/ol800357c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketone-, ester-, and amide-containing potassium trifluoroboratohomoenolates were prepared in good to excellent yields from the corresponding unsaturated carbonyl compounds. They were shown to be effective coupling partners in the Suzuki-Miyaura reaction with a variety of electrophiles including electron-rich and electron-poor aryl bromides and -chlorides.

引用

页码：1795 / 1798

页数：4

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