Catalytic monosilylation of 1,2-diols

被引：12
|
作者：
Takeichi, Tsubasa [1 ]
Kuriyama, Masami [1 ]
Onomura, Osamu [1 ]
机构：
[1] Nagasaki Univ, Grad Sch Biomed Sci, Nagasaki 8528521, Japan
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 49期
基金：
日本学术振兴会;
关键词：
Dimethyltin dichloride; 1,2-Diols; Silylation; Chemoselectivity; CHIRAL CU(II) COMPLEX; MESO-VIC-DIOLS; KINETIC RESOLUTION; SILYL ETHERS; CHEMOSELECTIVE DEPROTECTION; ASYMMETRIC BENZOYLATION; SYMMETRICAL 1,2-DIOLS; ORGANOTIN COMPOUNDS; CONVENIENT; ACYLATION;
D O I：
10.1016/j.tetlet.2011.10.016
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The selective monosilylation of 1,2-diols catalyzed by dimethyltin dichloride was successfully developed. This procedure was applied to various 1,2-diols, giving monosilylated products in good to excellent yields with high chemoselectivity. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6646 / 6648
页数：3
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