Novel dipolarophiles and dipoles in the metal-catalyzed enantioselective 1,3-dipolar cycloaddition of azomethine ylides

被引：385
|
作者：
Adrio, Javier [1 ]
Carretero, Juan C. [1 ]
机构：
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期
关键词：
ASYMMETRIC 3+2 CYCLOADDITION; NITRILE OXIDE CYCLOADDITIONS; DIVERSITY-ORIENTED SYNTHESIS; CHIRAL CALCIUM COMPLEXES; LEWIS-ACID; NITRONE CYCLOADDITIONS; BINAPHTHYLDIIMINE-NI(II) COMPLEXES; ALPHA; BETA-UNSATURATED ALDEHYDES; PYRROLIDINE DERIVATIVES; FULLERENE DERIVATIVES;
D O I：
10.1039/c1cc10779h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides constitutes one of the most powerful and atom economical methods for the enantioselective construction of pyrrolidines. This article highlights the recent developments in this area, with special focus on contributions improving the structural scope at the dipolarophile and azomethine ylide partners.
引用
收藏
页码：6784 / 6794
页数：11
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