Synthesis and Properties of SPEEK/PES Block Polymers

被引：0

作者：

Li Xue-Feng ^{[1
]}

Guo Mei-Mei ^{[1
]}

Liu Bai-Jun ^{[1
]}

Jiang Zhen-Hua ^{[1
]}

机构：

[1] Jilin Univ, Alan G McDiarmid Inst, Changchun 130012, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2011年 / 32卷 / 05期

关键词：

Proton exchange membrane; Polyaryletherketone; Polyarylethersulfone; Block polymer; FUEL-CELL; HYBRID;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two block SPEEK/PES copolymers were prepared via the postsulfonation reaction of the well designed precursors. The influence of microstructure on the properties of the membranes was investigated. The block copolymers had higher water uptake and proton conductivity in comparison with their random analogue. At 80 degrees C, the proton conductivities of the block copolymers were above 0.22 S/cm. The membranes of the block polymers exhibited obvious phase-separation microstructure. The study suggested that some properties could be improved by rational designing of the chemical architecture.

引用

页码：1022 / 1024

页数：3

共 7 条

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