An original synthesis of trans-1,2-diaminocyclobutane

被引：12

作者：

Vergne, F ^{[1
]}

Partogyan, K ^{[1
]}

Aitken, DJ ^{[1
]}

Husson, HP ^{[1
]}

机构：

[1] UNIV PARIS 05, FAC SCI PHARMACEUT & BIOL, URA 1310 CNRS, CHIM THERAPEUT LAB, F-75252 PARIS 06, FRANCE

来源：

TETRAHEDRON | 1996年 / 52卷 / 07期

关键词：

D O I：

10.1016/0040-4020(95)01091-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthesis of trans-1,2-diaminocyclobutane 1 is described in which the key feature is the novel stereoselective borane-induced reductive ring-expansion reaction of the cyclopropane-iminonitrile 2 to give the cyclobutane 4. This latter intermediate was also used to prepare a trans-fused rigid analogue of moclobemide.

引用

页码：2421 / 2428

页数：8

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