Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene

被引：99
|
作者：
Fan, Shilu [1 ]
Chen, Zhao [2 ]
Zhang, Xingang [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
[2] SW Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 18期
关键词：
C-H FUNCTIONALIZATION; ELECTRON-DEFICIENT POLYFLUOROARENES; BOND FORMATION; DIRECT ARYLATION; GENERAL-METHOD; SIMPLE ARENES; INDOLES; ACTIVATION; EFFICIENT; AZOLES;
D O I：
10.1021/ol3023165
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A copper-catalyzed dehydrogenative cross-coupling of benzothiazoles with thiazoles and polyfluoroarene under mild reaction conditions is described. This protocol provides a straightforward and operationally simple method for the synthesis of the 2,2'-linkage of thiazoles and 2-polyfluoroarylthiazoles of interest in life and material sciences.
引用
收藏
页码：4950 / 4953
页数：4
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