D-π-A Dye System Containing Cyano-Benzoic Acid as Anchoring Group for Dye-Sensitized Solar Cells

被引：41
|
作者：
Katono, Masataka [1 ]
Bessho, Takeru [1 ]
Meng, Sheng [2 ,3 ]
Humphry-Baker, Robin [1 ]
Rothenberger, Guido [1 ]
Zakeeruddin, Shaik M. [1 ]
Kaxiras, Efthimios [4 ,5 ]
Graetzel, Michael [1 ]
机构：
[1] Swiss Fed Inst Technol, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[2] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
[4] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
[5] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
来源：
LANGMUIR | 2011年 / 27卷 / 23期
基金：
瑞士国家科学基金会;
关键词：
CONVERSION-EFFICIENCY; CHARGE RECOMBINATION;
D O I：
10.1021/la203104v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A D-pi-A dye (KM-1) incorporating cyanobenzoic acid as a new acceptor/anchoring group has been synthesized for dye-sensitized solar cells (DSCs) with a high molar extinction coefficient of 66 700 M-1 cm(-1) at 437 nm. Theoretical calculations show that the hydrogen bond between -CN and surface hydroxyl leads to the most stable configuration on the surface of TiO2. In addition, the adsorption of the dye on TiO2 follows a Brunauer-Emmett-Teller (BET) isotherm. Multilayer adsorption of KM-1 on TiO2 seems to take place particularly at higher dye concentrations. DSC device using KM-1 reached a maximum incident photon-to-current conversion efficiency (IPCE) of 84%, with a solar to electric power conversion efficiency (PCE) of 3.3% at AM1.5 G illumination (100 mW cm(-2)). This new type of anchoring group paves a way to light harvesting with strong binding to the metal oxide surface. design new dyes that combine good visible
引用
收藏
页码：14248 / 14252
页数：5
相关论文
共 50 条
  • [1] Development of Dye-Sensitized Solar Cells Based on D-π-A Pyridinium Dye without Carboxylic Acid Moiety as Anchoring Group
    Ooyama, Yousuke
    Yamaguchi, Naoya
    Ohshita, Joji
    Harima, Yutaka
    [J]. ELECTROCHEMISTRY, 2013, 81 (05) : 325 - 327
  • [2] Development of a D-π-A dye with benzothienopyridine as the electron-withdrawing anchoring group for dye-sensitized solar cells
    Ooyama, Yousuke
    Sato, Takafumi
    Harima, Yutaka
    Ohshita, Joji
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (10) : 3293 - 3296
  • [3] Efficient near infrared D-π-A sensitizers with lateral anchoring group for dye-sensitized solar cells
    Hao, Yan
    Yang, Xichuan
    Cong, Jiayan
    Tian, Haining
    Hagfeldt, Anders
    Sun, Licheng
    [J]. CHEMICAL COMMUNICATIONS, 2009, (27) : 4031 - 4033
  • [4] Development of D-π-A dye with (pyridiniumyl)alkanesulfonate as electron-withdrawing anchoring group for dye-sensitized solar cell
    Ooyama, Yousuke
    Sato, Takafumi
    Enoki, Toshiaki
    Ohshita, Joji
    [J]. DYES AND PIGMENTS, 2015, 123 : 349 - 354
  • [5] Anchoring Groups for Dye-Sensitized Solar Cells
    Zhang, Lei
    Cole, Jacqueline M.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (06) : 3427 - 3455
  • [6] D-π-A Dyes that Contain New Hydantoin Anchoring Groups for Dye-Sensitized Solar Cells
    Masui, Hisashi
    Maitani, Masato M.
    Fuse, Shinichiro
    Yamamura, Ayaka
    Ogomi, Yuhei
    Hayase, Shuzi
    Kaiho, Tatsuo
    Tanaka, Hiroshi
    Wada, Yuji
    Takahashi, Takashi
    [J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (02) : 458 - 464
  • [7] What Is the Best Anchoring Group for a Dye in a Dye-Sensitized Solar Cell?
    Ambrosio, Francesco
    Martsinovich, Natalia
    Troisi, Alessandro
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (11): : 1531 - 1535
  • [8] A dye-sensitized solar cell containing an anchoring porphyrin
    Zhang, Qian
    Sun, Jing
    Shang, Ke-Xia
    Liu, Jia-Cheng
    Li, Ren-Zhi
    Jin, Neng-Zhi
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2017, 70 (05) : 780 - 789
  • [9] Development of D-π-A dyes with a pyrazine ring as an electron-withdrawing anchoring group for dye-sensitized solar cells
    Ooyama, Yousuke
    Uenaka, Koji
    Harima, Yutaka
    Ohshita, Joji
    [J]. RSC ADVANCES, 2014, 4 (57): : 30225 - 30228
  • [10] The effect of anchoring group number on the performance of dye-sensitized solar cells
    Shang, Huixia
    Luo, Yanhong
    Guo, Xiaozhi
    Huang, Xiaoming
    Zhan, Xiaowei
    Jiang, Kejian
    Meng, Qingbo
    [J]. DYES AND PIGMENTS, 2010, 87 (03) : 249 - 256
12345