Design and synthesis of charged porphyrin dimers for polyoxometalate recognition

被引：1

作者：

Lamare, Raphael ^{[1
]}

Ruppert, Romain ^{[1
]}

Elhabiri, Mourad ^{[2
]}

Ulrich, Gilles ^{[3
]}

Ruhlmann, Laurent ^{[1
]}

Weiss, Jean ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Chim Strasbourg, LJMR 7177, CNRS, 4 Rue Blaise Pascal, F-67000 Strasbourg, France

[2] European Sch Chem Polymers & Mat ECPM, Equipe Chim Bioorgan & Med, Lab Innovat Mol & Applicat LIMA, UMR7042,CNRS,Unistra,UHA,European Sch Chem Polyme, 25 Rue Becquerel, F-67087 Strasbourg, France

[3] ECPM, ICPEES Inst Chim & Proc Energie Environm & Sante, 25 Rue Becquerel, F-67087 Strasbourg, France

来源：

COMPTES RENDUS CHIMIE | 2021年 / 24卷

关键词：

Porphyrins; Polyoxometalates; Molecular recognition; Fluorescence quenching; Host-guest chemistry; VISIBLE-LIGHT; COMPLEX;

D O I：

10.5802/crchim.105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectroscopic methods and moderate affinities with log K-assoc varying from 2.6 to 4.2 have been determined and the parameters governing the formation of the complexes have been examined.

引用

页码：115 / 126

页数：12

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