Crystal structure of potassium tetraperoxomolybdate (VI) K2[Mo(O2)4]

被引：4

作者：

Grzywa, M ^{[1
]}

Rózycka, M ^{[1
]}

Lasocha, W ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

POWDER DIFFRACTION | 2005年 / 20卷 / 03期

关键词：

peroxomolybdate; powder diffraction; Rietveld refinement;

D O I：

10.1154/1.1997170

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Potassium tetraperoxomolybdate (VI) K-2[Mo(O-2)(4)] was prepared, and its X-ray powder diffraction pattern was recorded at low temperature (258 K). The unit cell parameters were refined to a = 10.7891(2) angstrom, alpha = 64.925(3)degrees, space group R-3c (167), Z = 6. The compound is isostructural with potassium tetraperoxotungstate (VI) K-2[W(O-2)(4)] (Stomberg, 1988). The sample of K-2[Mo(O-2)(4)] was characterized by analytical investigations, and the results of crystal structure refinement by Rietveld method are presented; final R-P and R-WP are 9.79% and 12.37%, respectively. (c) 2005 International Centre for Diffraction Data.

引用

页码：203 / 206

页数：4

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