Enantioselective formal synthesis of eleuthesides

被引：23
|
作者：
Ritter, N [1 ]
Metz, P [1 ]
机构：
[1] Tech Univ Dresden, Inst Organ Chem, D-01069 Dresden, Germany
来源：
SYNLETT | 2003年 / 15期
关键词：
antitumor agents; stereoselective addition reactions; organometallic reagents; intramolecular Diels-Alder reactions; chemoselectivo epimerization;
D O I：
10.1055/s-2003-42467
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An intramolecular Diels-Alder reaction of an enantiopure 3,5-hexadienyl acrylate and a chemoselective epimerization constitute the key steps of a highly stereoselective synthesis of triol 25, whose conversion to eleutherobin, eleuthosides A and B and sarcodictyins A and B is known.
引用
收藏
页码：2422 / 2424
页数：3
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