Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes Containing Chiral Boron as Stereogenic Unit

被引：31

作者：

Jimenez, Vicente G. ^{[1
]}

Santos, Fabio M. F. ^{[2
]}

Castro-Fernandez, Silvia ^{[1
]}

Cuerva, Juan M. ^{[1
]}

Gois, Pedro M. P. ^{[2
]}

Pischel, Uwe ^{[3
,4
]}

Campana, Araceli G. ^{[1
]}

机构：

[1] Univ Granada, Dept Organ Chem, Campus Univ Fuentenueva, E-18071 Granada, Spain

[2] Univ Lisbon, Res Inst Med iMed ULisboa, Fac Pharm, Ave Prof Gama Pinto, P-1649003 Lisbon, Portugal

[3] Univ Huelva, CIQSO Ctr Res Sustainable Chem, Campus El Carmen S-N, E-21071 Huelva, Spain

[4] Univ Huelva, Dept Chem, Campus El Carmen S-N, E-21071 Huelva, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 22期

关键词：

CHIROPTICAL PROPERTIES; ENANTIOSELECTIVE SYNTHESIS; ORGANIC-MOLECULES; FLUORESCENT; BODIPY; DYES; ABSORPTION; EFFICIENT; HELICENE; DESIGN;

D O I：

10.1021/acs.joc.8b01844

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Racemic mixtures of boronic acid-derived salicylidenehydrazone (BASHY) complexes were enantiomerically resolved. The chiroptical properties of the stereoisomers, containing an asymmetric boron as the only stereogenic unit, are translated into mirror-imaged electronic circular dichroism spectra and circularly polarized luminescence (CPL, dissymmetry factors of 3-5 x 10(-4)) is observed. The spectral position of the CPL emission is determined by the push-pull character of the dye. These features expand the functional scope of the brightly emitting BASHY dye platform.

引用

页码：14057 / 14062

页数：6

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