A novel green protocol for ligand free Suzuki-Miyaura cross-coupling reactions in WEB at room temperature

被引:134
|
作者
Boruah, Preeti Rekha [1 ]
Ali, Abdul Aziz [1 ]
Saikia, Bishwajit [1 ]
Sarma, Diganta [1 ]
机构
[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India
关键词
HETEROCYCLIC CARBENE COMPLEXES; ARYL CHLORIDES; CATALYSTS; HECK; PALLADIUM(II); BIARYLS; HALIDES;
D O I
10.1039/c4gc02522a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly efficient green protocol for palladium acetate-catalysed ligand-free Suzuki-Miyaura cross-coupling reactions in neat 'water extract of banana (WEB)' was developed. This method offers a mild, efficient and highly economical alternative to the existing protocols since the reaction proceeds in WEB at room temperature in air at very short reaction times (5-90 min) under 'ligand/external base/external promoter/organic medium' free conditions.
引用
收藏
页码:1442 / 1445
页数:4
相关论文
共 50 条
  • [1] Ligand-free, atom-efficient Suzuki-Miyaura type cross-coupling reactions at room temperature
    Zhou, Wen-Jun
    Wang, Ke-Hu
    Wang, Jin-Xian
    Gao, Zhi-Rong
    [J]. TETRAHEDRON, 2010, 66 (38) : 7633 - 7641
  • [2] Pd(OAc)2 in WERSA: a novel green catalytic system for Suzuki-Miyaura cross-coupling reactions at room temperature
    Boruah, Preeti Rekha
    Ali, Abdul Aziz
    Chetia, Mitali
    Saikia, Bishwajit
    Sarma, Diganta
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (57) : 11489 - 11492
  • [3] Conjugated Polymer Nanoparticles by Suzuki-Miyaura Cross-Coupling Reactions in an Emulsion at Room Temperature
    Muenmart, Duangratchaneekorn
    Foster, Andrew B.
    Harvey, Alan
    Chen, Ming-Tsz
    Navarro, Oscar
    Promarak, Vinich
    McCairn, Mark C.
    Behrendt, Jonathan M.
    Turner, Michael L.
    [J]. MACROMOLECULES, 2014, 47 (19) : 6531 - 6539
  • [4] Ligand-free Suzuki-Miyaura Cross-Coupling Reactions of Aryltriazenes with Arylboronic Acids
    Nan Guangming
    Zhu Fanghua
    Wei Zhijun
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (01) : 72 - 78
  • [5] Alcoholic solvent-assisted ligand-free room temperature Suzuki-Miyaura cross-coupling reaction
    Sarmah, Gayatri
    Mondal, Manoj
    Bora, Utpal
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (08) : 495 - 498
  • [6] Melamine as a versatile ligand for Suzuki-Miyaura cross-coupling
    Trafford, Mitchell A.
    Hamilton, Alaina E.
    Buxton, Audrey M.
    Chalker, Justin M.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [7] Suzuki-miyaura cross-coupling reactions of potassium alkenyltrifluoroborates
    Molander, GA
    Bernardi, CR
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (24): : 8424 - 8429
  • [8] Stereospecific and stereoselective Suzuki-Miyaura cross-coupling reactions
    Department of Chemistry, Queen's University, Kingston
    ON
    K7L 3N6, Canada
    [J]. RSC Catal. Ser., 21 (521-550):
  • [9] Suzuki-Miyaura Cross-Coupling Reactions of Unprotected Haloimidazoles
    Tan, Jiajing
    Chen, Yonggang
    Li, Hongmei
    Yasuda, Nobuyoshi
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (18): : 8871 - 8876
  • [10] Orbital phase in Suzuki-Miyaura cross-coupling reactions
    Inagaki, Satoshi
    Ikeda, Hirotaka
    [J]. TETRAHEDRON LETTERS, 2014, 55 (14) : 2223 - 2225