Pd-catalyzed bidentate auxiliary assisted remote C(sp3)-H functionalization

被引：11

作者：

Talukdar, Kangkan ^{[1
]}

Shah, Tariq A. ^{[2
]}

Sarkar, Tanumay ^{[1
]}

Roy, Subhasish ^{[3
]}

Maharana, Prabhat Kumar ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India

[2] Univ Kashmir, Dept Chem, Srinagar 190006, India

[3] Assam Don Bosco Univ, Sch Fundamental & Appl Sci, Dept Chem, Sonapur 782402, India

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 98期

关键词：

C-H BONDS; REMOVABLE DIRECTING GROUP; ALPHA-AMINO-ACIDS; CROSS-COUPLING REACTIONS; UNACTIVATED C(SP(3))-H; C(SP(2))-H BONDS; INTRAMOLECULAR AMINATION; COOPERATIVE CATALYSIS; DIRECT ARYLATION; GAMMA;

D O I：

10.1039/d1cc05291h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd-catalyzed C-H functionalisation affords effective synthetic tools to construct C-C and C-X bonds. Despite the challenges, the distal functionalization of C(sp(3))-H bonds has witnessed significant developments and the use of bidentate auxiliaries has garnished this area by providing an opportunity to control reactivity as well as selectivity beyond proximal sites. This article covers the recent developments on the Pd-catalyzed bidentate auxiliary-assisted distal C(sp(3))-H functionalization and is categorized based on the nature of functionalizations.

引用

页码：13221 / 13233

页数：13

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