Correlations between composition and crystallinity of LDPE/HDPE blends

被引:68
|
作者
Munaro, Marilda [2 ]
Akcelrud, Leni [1 ]
机构
[1] Univ Fed Parana, Dept Quim, BR-81531990 Curitiba, Parana, Brazil
[2] LACTEC, Inst Tecnol Desenvolvimento, BR-81531990 Curitiba, Parana, Brazil
关键词
HDPE; LDPE; polyethylene blends; morphology; DMTA;
D O I
10.1007/s10965-007-9146-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
DMTA, DSC, WAXS and density were used to quantify the crystallinity and crystallite dimensions of specific grades of LDPE/HDPE blends. In virtue of the close agreement of the results obtained with the three techniques, an average degree of crystallinity was calculated, allowing the establishment of quantitative relationships between composition and crystallinity, and shifting of the alpha-relaxation. Dimensions along the 110 and 200 planes were also correlated with shifting of the alpha-transition.
引用
收藏
页码:83 / 88
页数:6
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