Calix[4]pyrrole: An old yet new ion-pair receptor

被引：275
|
作者：
Custelcean, R
Delmau, LH
Moyer, BA
Sessler, JL
Cho, WS
Gross, D
Bates, GW
Brooks, SJ
Light, ME
Gale, PA
机构：
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Univ Texas, Inst Cell & Mol Biol, Dept Chem & Biochem, Austin, TX 78712 USA
[3] Univ Southampton, Sch Chem, Southampton SO17 1WD, Hants, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 17期
基金：
英国工程与自然科学研究理事会;
关键词：
calix compounds; crystal engineering; hydrogen bonds; ion pairs; supramolecular chemistry;
D O I：
10.1002/anie.200462945
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ditopic cation-anion binding is revealed by solid-state studies of the anion-recognition behavior of the calix[4]pyrrole unit. Anion binding causes an electron-rich conelike cavity to be formed that can then bind large polarizable cations. Furthermore, complexation of calix[4]pyrrole with cesium carbonate results in dimerization, in which a single anion bridges two calix[4]pyrroles (see the crystal structure of the Cs2CO3 complex). (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2537 / 2542
页数：6
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