The effect of additives on radiation-induced grafting of AA and SSS onto HDPE

被引:12
|
作者
Zu, Jianhua [1 ]
Hu, Zhiqiang
Wang, Weitao
Zhang, Jianqiu
Pino, E. S.
Gu, Jianzhong
Tong, Long
机构
[1] Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
[2] CNEN SP, IPEN, Sao Paulo, Brazil
基金
中国国家自然科学基金;
关键词
D O I
10.1007/s10967-007-6816-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A kind of ion-exchange membrane with strong acid and weak acid groups was prepared by radiation-induced grafting of acrylic acid (AA) and sodium styrene sulfonate (SSS) onto high-density polyethylene membrane (HDPE). The effect of additives such as sodium acetate, sodium chloride on grafting yield was studied. It was found that for either pre-irradiation method or simultaneous radiation method, the weak acid salt of strong alkali sodium acetate had a complex effect on the grafting yield by "pH effect" and "ion pair effect", and the neutral salt sodium chloride was helpful to the increase of grafting yield by "ion pair effect".
引用
收藏
页码:479 / 484
页数:6
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