Paramagnetic metal complexes of diamido donor ligands

被引：6
|
作者：
Hayes, Cassandra E. [1 ]
Leznoff, Daniel B. [1 ]
机构：
[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 19期
基金：
加拿大自然科学与工程研究理事会;
关键词：
TANTALUM DINITROGEN COMPLEX; ON BOUND DINITROGEN; N BOND-CLEAVAGE; ZIRCONIUM COMPLEXES; ALKYL COMPLEXES; DIAMIDOPHOSPHINE COMPLEXES; SIDE-ON; COORDINATED DINITROGEN; REDUCTIVE CLEAVAGE; GROUP-4; COMPLEXES;
D O I：
10.1039/c1dt11559f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recently, considerable attention has been given to the use of multi-dentate amido ligands in the coordination chemistry of a range of transition metals as a means of accessing novel structural motifs and unusual reactivity. Presented herein is a perspective on transition and f-block metal complexes containing diamido donor ligands of the general form [NDN](2-) (D = NR, O, PR). Particular focus is given to paramagnetic metals, which have in general been studied much less than their diamagnetic counterparts despite their potential to exhibit unique structures and diverse reactivity patterns, in addition to their magnetic properties.>
引用
收藏
页码：5743 / 5753
页数：11
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