Monomer reactivity ratios and Q,e-values of trialkylsilyl acrylates and methacrylates

被引：3
|
作者：
Fujiwara, H [1 ]
Narita, T [1 ]
Hamana, H [1 ]
机构：
[1] Saitama Inst Technol, Dept Appl Chem, Okabe, Saitama 3690293, Japan
来源：
POLYMER JOURNAL | 2001年 / 33卷 / 01期
关键词：
monomer reactivity ratios; Q; e; tributylsilyl methacrylate; tri(iso-propyl)silyl methacrylate; tri(iso-butyl) silyl methacrylate; tributylsilyl acrylate; tri-(iso-propyl)silyl acrylate;
D O I：
10.1295/polymj.33.102
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The monomer reactivity ratio and Q, e of trialkylsilyl methacrylates and acrylates were studied. Copolymerizations of trialkylsilyl acrylates and methacrylates (M1) with styrene (M2) were carried out in bulk with sealed tube under nitrogen atmosphere at 80°C initiated by BPO. Copolymer composition of each monomer unit in copolymer was obtained from 1H NMR measurement. Monomer reactivity ratios were determined by the Kelen-Tudos method.
引用
收藏
页码：102 / 103
页数：2
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