Highly efficient and reusable polystyrene-supported copper(II) catalytic system for S-arylation of potassium thiocyanate by aryl halides in water

被引:10
|
作者
Hajipour, Abdol R. [1 ,2 ]
Jajarmi, Saeideh [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Dept Pharmacol, Sch Med, 1300 Univ Ave, Madison, WI 53706 USA
关键词
copper(II) catalyst; C-S coupling; symmetric diaryl sulfides; heterogeneous catalyst; aryl halides; SONOGASHIRA COUPLING REACTIONS; AEROBIC CONDITIONS; PD(II) COMPLEX; SUZUKI; HECK; NANOPARTICLES; INHIBITORS; SOLVENT; THIOLS;
D O I
10.1002/aoc.3471
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An inexpensive, efficient and environmentally friendly copper(II) catalyst supported on polystyrene was successfully synthesized and used as a heterogeneous catalyst for S-arylation of potassium thiocyanate by aryl halides. Also this catalyst could be recovered and reused several times without any noticeable decrease in its catalytic activity. Copyright (C) 2016 John Wiley & Sons, Ltd.
引用
收藏
页码:566 / 570
页数:5
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    Perumgani, Pullaiah C.
    Mandapati, Mohan Rao
    [J]. APPLIED CATALYSIS A-GENERAL, 2014, 483 : 110 - 115
  • [2] A highly efficient and widely functional-group-tolerant catalyst system for copper(I)-catalyzed S-arylation of thiols with aryl halides
    Feng, Yang
    Wang, Huifeng
    Sun, Fangfang
    Li, Yaming
    Fu, Xinmei
    Jin, Kun
    [J]. TETRAHEDRON, 2009, 65 (47) : 9737 - 9741
  • [3] Efficient Copper(I)-Catalyzed S-Arylation of KSCN with Aryl Halides in PEG-400
    Li Xiaokang
    Yuan Tangjun
    Chen Junmin
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (03) : 651 - 655
  • [4] An efficient iron-catalyzed S-arylation of aryl and alkylthiols with aryl halides in the presence of water under aerobic conditions
    Sindhu, K. S.
    Thankachan, Amrutha P.
    Thomas, Anns Maria
    Anilkumar, Gopinathan
    [J]. TETRAHEDRON LETTERS, 2015, 56 (34) : 4923 - 4926
  • [5] EFFICIENT COPPER-CATALYZED DOUBLE S-ARYLATION OF ARYL HALIDES WITH SODIUM SULFIDE IN PEG-400
    Chen, Junmin
    Zhang, Yimin
    Liu, Li
    Yuan, Tangjun
    Yi, Fei
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2012, 187 (11) : 1284 - 1290
  • [6] N-arylation of indoles with aryl halides using copper/glycerol as a mild and highly efficient recyclable catalytic system
    Yadav, Dilip Kumar T.
    Rajak, Sanil S.
    Bhanage, Bhalchandra M.
    [J]. TETRAHEDRON LETTERS, 2014, 55 (04) : 931 - 935
  • [7] Simple and efficient recyclable catalytic system for performing copper-catalysed S-arylation reactions in the presence of water
    Carril, Monica
    SanMartin, Raul
    Dominguez, Esther
    Tellitu, Imanol
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (18) : 5100 - 5105
  • [8] Highly Efficient and Reusable Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl Halides
    Kim, A. Young
    Lee, Hyun Ju
    Park, Ji Chan
    Kang, Hyunju
    Yang, Haesik
    Song, Hyunjoon
    Park, Kang Hyun
    [J]. MOLECULES, 2009, 14 (12) : 5169 - 5178
  • [9] Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions
    Xu, Hua-Jian
    Liang, Yu-Feng
    Zhou, Xin-Feng
    Feng, Yi-Si
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (13) : 2562 - 2568
  • [10] Highly efficient and magnetically separable nano-CuFe2O4 catalyzed S-arylation of thiourea by aryl/heteroaryl halides
    Hajipour, Abdol R.
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    Azizi, Ghobad
    [J]. CHINESE CHEMICAL LETTERS, 2014, 25 (10) : 1382 - 1386