An extensive study of bromination of cis,trans,trans-1,5,9-cyclododecatriene:: product structures and conformations

被引:11
|
作者
Smith, K
Liu, CH
El-Hiti, GA
Kang, GS
Jones, E
Clement, SG
Checquer, AD
Howarth, OW
Hursthouse, MB
Coles, SJ
机构
[1] Univ Wales Swansea, Dept Chem, Ctr Clean Chem, Swansea SA2 8PP, W Glam, Wales
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[3] Univ Wales Coll Cardiff, Dept Chem, Cardiff CF1 3TB, S Glam, Wales
[4] Tanta Univ, Fac Sci, Dept Chem, Tanta 31527, Egypt
关键词
D O I
10.1039/b417156j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Bromine has been added to cis, trans, trans-1,5,9-cyclododecatriene under various reaction conditions. All expected direct addition products have been isolated, and their structures have been determined by microanalysis, NMR and X-ray crystallography. Advanced NMR techniques were used to determine solution conformations of several of the compounds, enabling comparison with the solid-state conformations obtained by crystallography.
引用
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页码:1880 / 1892
页数:13
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