High-yielding cleavage of (Aryloxy)acetates

被引：24
|
作者：
Spurg, Anke [1 ]
Waldvogel, Siegfried R. [1 ]
机构：
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 02期
关键词：
azides; cleavage reactions; carboxylic acids; arenes; rearrangement;
D O I：
10.1002/ejoc.200700769
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A reliable and high-yielding one-pot sequence for the removal of O-carboxymethyl moieties from phenols is presented. When diethylphosphoryl. azide is employed as the azide transfer reagent in the Curtius rearrangement and glycerol in the subsequent hydrolytic workup, the protocol can be reliably applied to a very broad scope of substrates. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
引用
收藏
页码：337 / 342
页数：6
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